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Tellurium was discovered in1783 by Baron Franz Joseph Müller von Reichenstein at Sibiu, Romania.
[Latin, tellus = earth]
French: tellure
German: tellur
Italian: tellurio
Spanish: teluro
Description: Tellurium is a silvery-white, metallic-looking in bulk, but is usually obtained as a dark grey powder. It is a semi-metal. Tellurium burns in air or oxygen, is unaffected by water or HCl, but dissolves in HNO3. It is used in alloys to improve machinability, in electronics, and in catalysts.
State: | Single crystal |
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Crystal structure: | Hexagonal |
Production method: | Czochralski |
Standard size: | diameter 10mm thickness 1-2mm |
Orientation: | (0001), (1100) and (11-20) |
Orientation accuracy: | <2°, <1°, <0.4° or <0.25° |
Polishing: | as cut, one or two sides polished |
Roughness of surface: | <0.03µm |
Purity: | 99.999% |
Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
Density: | 6.24 g/cm3 |
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Melting point: | 449.55 °C / 722.7 °K |
Boiling point: | 989.85 °C / 1263.0 °K |
Molar volume: | 20.45 cm3 |
Thermal conductivity: | 2.35 [300 K] Wm-1K-1 |
Coefficient of linear thermal expansion: | 16.75 x 10-6 K-1 |
Electrical resistivity: | 4.36x 10-3 [298 K] Wm |
Mass magnetic susceptibility: | -3.9 x 10-9(s) kg-1m3 |
Young's modulus: | 47.1 GPa |
Rigidity modulus: | 16.7 GPa |
Bulk modulus: | n.a. GPa |
Poisson's ratio: | 0.16 - 0.3 |
Radii: | Te3+ 56; Te4+ 97; Te2- 211; atomic 143; covalent 1 |
Electronegativity: | 2.1 (Pauling); 2.01 (Allred); 5.49 eV (absolute) |
Effective nuclear charge: | 6.95 (Slater); 10.81 (Clementi); 13.51 (Froese-Fischer) |
Number of Isotopes (incl. nuclear isomers): | 39 |
Issotope mass range: | 108 -> 137 |
Crystal structure, (cell dimentions / pm), space group | Hexagonal |
X-ray diffraction: mass absorption coefficients: | CuKα 282 (µ/r) / cm2g-1 MoKα 35.0 (µ/r) / cm2g-1 |
Neutron scattering length: | 0.580 b/10-12 cm |
Thermal neutron capture cross-section: | 4.7 sa / barns |
Biological role: | none |
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Toxicity | |
Toxic intake: | Elemental tellurium has low toxicity but unpleasant side effects, producing extremely unpleasant bre |
Lethal intake: | 2 g of sodium tellurite has proved fatal to a human. LD50 (Te metal, oral, rat)= 83 mg kg-1 |
Hazards: | Tellurium compounds are toxic by ingestion and intravenous routes. They are also considered to be experimental tetratogens. |
Level in humans | |
Blood: | 0.0055 mg dm-3 |
Bone: | n.a. |
Liver: | 0.014 p.p.m. |
Muscle: | 0.017 p.p.m. |
Daily dietary intake: | c. 0.6 mg |
Total mass of element in average [70 kg] person: | c. 0.7 mg |
Mineral | Formula | Density | Hardness | Crystal apperance |
---|---|---|---|---|
Sylvanite | AgAuTe4 | 8.16 | 1.5 - 2 | mon., met. grey |
Tellurite | TeO2 | 5.90 | 2 | orth., sub-adamantine white |
Chief ore: | none mined as such. Tellurium is obtained from the anode slime of copper refining. |
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World production: | 215 tonnes/year |
Main mining areas: | Sylvanite in Australia, USA and Romania |
Reserves: | n.a. |
Specimen: | available as granules, ingots, pieces or powder. DANGER ! |
Abundances | |
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Sun: | n.a. |
Earth's crust: | c. 0.005 p.p.m. |
Seawater: | |
Residence time: | |
Classification: | scavenged |
Oxidation state: | IV and VI; mainly VI |
Source: Emsley, J. (1998) The Elements (3rd Edition)