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Known to ancient civilizations.
French: plomb
German: blei
Italian: piombo
Spanish: plomo
Description: Lead is a soft, weak, ductile, dull grey metal that tarnishes in moist air but is stable to oxygen and water. It dissolves in HNO3. Lead is used in batteries, cables, glass, solder, radiation shielding, etc. A little is still used in paints and petrol but generally this use is being phased out.
| State: | single crystal |
|---|---|
| Crystal structure: | fcc |
| Production method: | Bridgman |
| Standard size: | diameter 10-12mm thickness 1-2mm |
| Orientation: | (100), (110) and (111) |
| Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
| Polishing: | electrochemical |
| Roughness of surface: | <0.03µm |
| Purity: | 99.99% |
| Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
| Density: | 11.4 g/cm3 |
|---|---|
| Melting point: | 327.50 °C / 600.65 °K |
| Boiling point: | 1739.85 °C / 2013 °K |
| Molar volume: | 18.26 cm3 |
| Thermal conductivity: | 35.3 [300 K] Wm-1K-1 |
| Coefficient of linear thermal expansion: | 29.1 x 10-6 K-1 |
| Electrical resistivity: | 20.648x 10-8 [293 K] Wm |
| Mass magnetic susceptibility: | -1.39 x 10-9(s) kg-1m3 |
| Young's modulus: | 16.1 GPa |
| Rigidity modulus: | 5.59 GPa |
| Bulk modulus: | 45.8 GPa |
| Poisson's ratio: | 0.44 |
| Radii: | Pb4+ 84; Pb2+ 132; atomic 175; covalent 154 |
| Electronegativity: | 2.33 (Pauling); 1.55 (Allred); 3.90 eV (absolute) |
| Effective nuclear charge: | 5.65 (Slater); 12.39 (Clementi); 15.33 (Froese-Fischer) |
| Number of Isotopes (incl. nuclear isomers): | 41 |
| Issotope mass range: | 184 -> 214 |
| Crystal structure, (cell dimentions / pm), space group | fcc |
| X-ray diffraction: mass absorption coefficients: | CuKα 232 (µ/r) / cm2g-1 MoKα 120 (µ/r) / cm2g-1 |
| Neutron scattering length: | 0.9405 b/10-12 cm |
| Thermal neutron capture cross-section: | 0.171 sa / barns |
| Biological role: | none |
|---|---|
| Toxicity | |
| Toxic intake: | c. 50 mg - 100 g |
| Lethal intake: | LD50 (acetate, intravenous, mouse)=104 mg kg-1 |
| Hazards: | Lead is moderately toxic by ingestion and affects the gut and central nervous system and causes anaemia. However, most ingested lead passes through the body without being absorbed. It is a cumulative |
| Level in humans | |
| Blood: | 0.21 mg dm-3 |
| Bone: | 3.6 - 30 p.p.m. |
| Liver: | 3 - 12 p.p.m. |
| Muscle: | 0.23 - 3.3 p.p.m. |
| Daily dietary intake: | 0.06 - 0.5 mg |
| Total mass of element in average [70 kg] person: | 120 mg (stored in skeleton) |
| Mineral | Formula | Density | Hardness | Crystal apperance |
|---|---|---|---|---|
| Anglesite | PbSO4 | 6.38 | 2.5 - 3 | orth., adam./greasy white |
| Boulangerite | Pb5Sb4S11 | 6.23 | 2.5 - 3 | orth., met. bluish-grey |
| Bournonite | PbCuSbS3 | 5.8 | 2.5 - 3 | orth., met. steel-grey |
| Cerussite | PbCO3 | 6.55 | 3 - 3.5 | orth., adam./vit. Col. |
| Galena | PbS | 7.58 | 2.6 | cub., met. grey |
| Minium | Pb3O4 | 9.05 | 2.5 | tet., greasy red/brown |
| Pyromorphite | Pb5(PO4)3Cl | 7.04 | 3.5 - 4 | hex., barrel-shaped crystals, often hollow |
| Chief ore: | galena is the main ore (with silver as a by-product), pyromorphite, boulangerite and cerussite are m |
|---|---|
| World production: | 2.8 x 106 tonnes/year |
| Main mining areas: | galena in USA, Australia, Mexico, West Germany; boulangerite in France. |
| Reserves: | 85 x 106 tonnes |
| Specimen: | available as foil, granules, ingots, powder, rod, shot and wire. CARE ! |
| Abundances | |
|---|---|
| Sun: | 85.1 (relative to H = 1 x 1012) |
| Earth's crust: | 14 p.p.m. |
| Seawater: | |
| Residence time: | |
| Classification: | scavenged |
| Oxidation state: | II |
Source: Emsley, J. (1998) The Elements (3rd Edition)