Lead (Pb)

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Lead 82Pb207.19


Known to ancient civilizations.

French: plomb
German: blei
Italian: piombo
Spanish: plomo


Description: Lead is a soft, weak, ductile, dull grey metal that tarnishes in moist air but is stable to oxygen and water. It dissolves in HNO3. Lead is used in batteries, cables, glass, solder, radiation shielding, etc. A little is still used in paints and petrol but generally this use is being phased out.

 

 

Lead single crystal properties

State: single crystal
Crystal structure: fcc
Production method: Bridgman
Standard size: diameter 10-12mm
thickness 1-2mm
Orientation: (100), (110) and (111)
Orientation accuracy: <2°, <1°, <0.4° or <0.1°
Polishing: electrochemical
Roughness of surface: <0.03µm
Purity: 99.99%
Typical analysis (ppm): C 3
H < 1
O 9
N < 5
Cu 1.60
Fe 1.80
Ni < 1
Pb 0.30
Si 0.30

 
Ga, Hf and Ta are below the detection limit
 

Materials properties

Density: 11.4 g/cm3
Melting point: 327.50 °C / 600.65 °K
Boiling point: 1739.85 °C / 2013 °K
Molar volume: 18.26 cm3
Thermal conductivity: 35.3 [300 K] Wm-1K-1
Coefficient of linear thermal expansion: 29.1 x 10-6 K-1
Electrical resistivity: 20.648x 10-8 [293 K] Wm
Mass magnetic susceptibility: -1.39 x 10-9(s) kg-1m3
Young's modulus: 16.1 GPa
Rigidity modulus: 5.59 GPa
Bulk modulus: 45.8 GPa
Poisson's ratio: 0.44
Radii: Pb4+ 84; Pb2+ 132; atomic 175; covalent 154
Electronegativity: 2.33 (Pauling); 1.55 (Allred); 3.90 eV (absolute)
Effective nuclear charge: 5.65 (Slater); 12.39 (Clementi); 15.33 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 41
Issotope mass range: 184 -> 214
Crystal structure, (cell dimentions / pm), space group fcc
X-ray diffraction: mass absorption coefficients: CuKα 232 (µ/r) / cm2g-1
MoKα 120 (µ/r) / cm2g-1
Neutron scattering length: 0.9405 b/10-12 cm
Thermal neutron capture cross-section: 0.171 sa / barns

 


Biological data

Biological role: none
Toxicity  
Toxic intake: c. 50 mg - 100 g
Lethal intake: LD50 (acetate, intravenous, mouse)=104 mg kg-1
Hazards: Lead is moderately toxic by ingestion and affects the gut and central nervous system and causes anaemia. However, most ingested lead passes through the body without being absorbed. It is a cumulative
Level in humans  
Blood: 0.21 mg dm-3
Bone: 3.6 - 30 p.p.m.
Liver: 3 - 12 p.p.m.
Muscle: 0.23 - 3.3 p.p.m.
Daily dietary intake: 0.06 - 0.5 mg
Total mass of element in average [70 kg] person: 120 mg (stored in skeleton)

 


Geological data

MineralFormulaDensityHardnessCrystal apperance
Anglesite PbSO4 6.38 2.5 - 3 orth., adam./greasy white
Boulangerite Pb5Sb4S11 6.23 2.5 - 3 orth., met. bluish-grey
Bournonite PbCuSbS3 5.8 2.5 - 3 orth., met. steel-grey
Cerussite PbCO3 6.55 3 - 3.5 orth., adam./vit. Col.
Galena PbS 7.58 2.6 cub., met. grey
Minium Pb3O4 9.05 2.5 tet., greasy red/brown
Pyromorphite Pb5(PO4)3Cl 7.04 3.5 - 4 hex., barrel-shaped crystals, often hollow

 

Chief ore: galena is the main ore (with silver as a by-product), pyromorphite, boulangerite and cerussite are m
World production: 2.8 x 106 tonnes/year
Main mining areas: galena in USA, Australia, Mexico, West Germany; boulangerite in France.
Reserves: 85 x 106 tonnes
Specimen: available as foil, granules, ingots, powder, rod, shot and wire. CARE !

 

Abundances  
Sun: 85.1 (relative to H = 1 x 1012)
Earth's crust: 14 p.p.m.
Seawater:  
Residence time:  
Classification: scavenged
Oxidation state: II

Source: Emsley, J. (1998) The Elements (3rd Edition)


Overview of elements with access to our shop

1 18
H
2 13 14 15 16 17
He
Li Be B C
N
O
F
Ne
Na Mg 3 4 5 6 7 8 9 10 11 12 Al Si P S
Cl
Ar
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se
Br
Kr
Rb Sr Y Zr Nb Mo
Tc
Ru Rh Pd Ag Cd In Sn Sb Te I
Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi
Po
At
Ra
Fr
Ra
Ac
Ce Pr Nd
Pm
Sm Eu Gd Tb Dy Ho Er Tm Yb Lu


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