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Discovered in 1925 by W. Noddack, Ida Tacke and O. Berg at Berlin, Germany.
[Greek, Rhenus = river Rhine]
French: Rhénium
German: Rhenium
Italian: Renio
Spanish: Renio
Description: Rhenium is a silvery metal, but is usually obtained as a grey powder. It resists corrosion but slowly tarnishes in moist air. Rhenium dissolves in HNO3 an H2SO4. It is used in filaments, thermistors and catalysts.
State: | Single crystal |
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Crystal structure: | hexagonal |
Production method: | Floating zone |
Standard size: | diameter 6mm thickness 1-2mm |
Orientation: | (0001), (1-100) and (11-20) |
Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
Polishing: | as cut, one or two sides polished |
Roughness of surface: | <0.03µm |
Purity: | 99.99% |
Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
Density: | 12.4 g/cm3 |
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Melting point: | 3179.85 °C / 3453 °K |
Boiling point: | 5626.85 °C / 5900 °K |
Molar volume: | 8.86 cm3 |
Thermal conductivity: | 47.9 [300 K] Wm-1K-1 |
Coefficient of linear thermal expansion: | 6.63 x 10-6 K-1 |
Electrical resistivity: | 19.3x 10-8 [293 K] Wm |
Mass magnetic susceptibility: | +4.56 x 10-9(s) kg-1m3 |
Young's modulus: | 466 GPa |
Rigidity modulus: | 181 GPa |
Bulk modulus: | 334 GPa |
Poisson's ratio: | 0.26 |
Radii: | Re7+ 60; Re6+ 61; Re4+ 72; atomic 137; covalent 12 |
Electronegativity: | 1.9 (Pauling); 1.46 (Allred); 4.02 eV (absolute) |
Effective nuclear charge: | 3.60 (Slater); 10.12 (Clementi); 14.62 (Froese-Fischer) |
Number of Isotopes (incl. nuclear isomers): | 34 |
Issotope mass range: | 162 -> 192 |
Crystal structure, (cell dimentions / pm), space group | hexagonal |
X-ray diffraction: mass absorption coefficients: | CuKα 179 (µ/r) / cm2g-1 MoKα 103 (µ/r) / cm2g-1 |
Neutron scattering length: | 0.92 b/10-12 cm |
Thermal neutron capture cross-section: | 89.7 sa / barns |
Biological role: | none |
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Toxicity | |
Toxic intake: | n.a. |
Lethal intake: | LD50 (ReCl3, intraperitoneal, mouse)= 280 mg kg-1 |
Hazards: | There are no reported cases of humans beeing affected by rhenium. Like other powdered metals, rhenium dust could pose a moderate fire or explosion hazard. |
Level in humans | |
Blood: | |
Bone: | |
Liver: | |
Muscle: | |
Daily dietary intake: | n.a. |
Total mass of element in average [70 kg] person: | n.a., but very low |
Mineral | Formula | Density | Hardness | Crystal apperance |
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Chief ore: | Rhenium is extracted from the flue dusts of molybdenum smelters. |
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World production: | 4.5 tonnes/year |
Main mining areas: | see molybdenum |
Reserves: | 3500 tonnes |
Specimen: | available as foil, powder, ribbon or wire. CARE ! |
Abundances | |
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Sun: | <2 (relative to H = 1 x 1012) |
Earth's crust: | 4 x 10-4 p.p.m. |
Seawater: | |
Residence time: | |
Classification: | |
Oxidation state: | III |
Source: Emsley, J. (1998) The Elements (3rd Edition)