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Holmium was discoverd in 1878 by P.T. Cleve at Uppsala, Sweden, and independently by M. Delafontaine and J.L. Soret at Geneva, Switzerland.
[Greek: Holmia = Sweden]
French: holmium
German: holmium
Italian: olmio
Spanish: holmio
Description: Holmium is a silvery metal of the so-called rare earth group (more correctly termed the lanthanides). It is slowly attacked by oxygen and water, and dissolves in acids. Holmium is used as a flux concentrator for high magnetic fields.
State: | Single crystal |
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Crystal structure: | hexagonal |
Production method: | Floating zone |
Standard size: | diameter 7-8mm thickness 1mm |
Orientation: | (0001) |
Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
Polishing: | as cut, one or two sides polished |
Roughness of surface: | <0.03 µm |
Purity: | 99.99% |
Crystal structure: | (cell dimensions/pm), space group a-Ho h.c.p. (a=357.73, c=561.58), P63/mmc b-Ho b.c.c. (a=396), Im3m T(a -> a)= just below melting point High pressure form: (a=334, c=2410), R3m |
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X-ray diffractions mass absorption coefficients: | CuKa 128 (µ/r) / cm2g-1 MoKa 73.9 (µ/r) / cm2g-1 |
Neutron scattering length: | 0.808 b/10-12 cm |
Thermal neutron capture cross-section: | 65 sa / barns |
Density: | 8.8 kg/m-3 [293 K]; 2390 [liquid at m.p.] |
Melting point: | 1473.85 °C / 1747 °K |
Boiling point: | 2694.85 °C / 2968 °K |
Molar volume: | 18.75 cm3 |
Thermal conductivity: | 16.2 [300 K] Wm-1K-1 |
Coefficient of linear thermal expansion: | 9.5 x 10-6 K-1 |
Electrical resistivity: | 87.0 x 10-8 [293 K] Wm |
Mass magnetic susceptibility: | +5.49 x 10-6(s) kg-1m3 |
Young's modulus: | 64.8 GPa |
Rigidity modulus: | 26.3 GPa |
Bulk modulus: | 40.2 GPa |
Poisson's ratio: | 0.231 GPa |
Radi: | Ho3+ 89; atomic 177; covalent 158 |
Electronegativity: | 1.23 (Pauling); 1.10 (Allred); £3.3 eV (absolute) |
Effective nuclear charge: | 2.85 (Slater); 8.44 (Clementi); 11.60 (Froese-Fischer) |
Number of Isotopes (incl. nuclear isomers): | 39 |
Isotope mass range: | 148 -> 170 |
Biological role: | none, but acts to stimulate metabolism |
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Toxicity | |
Toxic intake: | n.a. |
Lethal intake: | LD50 (chloride, oral, mouse)=7200 mg kg-1 |
Hazards: | Holmium is mildly toxic by ingestion |
Level in humans | |
Organs: | n.a., but low |
Daily dietary intake: | n.a. |
Total mass of element in average [70 kg] person: |
n.a. |
Minerals: | Many minerals are known, and aluminium is present in many other minerals | |||
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Mineral | Formula | Density | Hardness | Crystal apperance |
Bastnäsite | (Ce, La etc.) Co3F | 4.9 | 4 - 4.5 | hex., vit./greasy yellow |
Monazite | (Ce, La, Nd, Th etc.) PO4 | 5.20 | 5 - 5.5 | mon., waxy/vit., yellow-brown |
Chief ore: | monazite, bastnäsite |
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World production: | c. 10 tonnes/year |
Main mining areas: | USA, Brazil, India, Sri Lanka, Australia, China |
Reserves: | 4 x 105 tonnes |
Specimen: | available as ingots or granules. Safe. |
Abundances | |
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Sun: | n.a. |
Earth's crust: | 1.4 ppm |
Seawater: | |
Atlantic surface: | 2.4 x 10-7 ppm |
Atlantic deep: | 2.9 x 10-7 ppm |
Pacific surface: | 1.6 x 10-7 ppm |
Pacific deep: | 5.8 x 10-7 ppm |
Residence time: | n.a. |
Classification: | recycled |
Oxidation state: | III |
Other sizes and specifications on request