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Lutetium was discovered in 1907 by G. Urbain at Paris, France, and independently by C. James at the Universität of New Hampshire, USA.
[Greek, Lutetia = Paris]
French: lutétium
German: Lutetium
Italian: lutezio
Spanish: lutecio
Description: Lutetium is the hardest, densest and one of the rarest so-called rare-earth metals. It is little used except in chemical research.
| Crystal structure: |
(cell dimensions/pm), space group, |
|---|---|
| X-ray diffractions mass absorption coefficients: | CuKa 153 (µ/r) / cm2g-1 MoKa 88.2 (µ/r) / cm2g-1 |
| Neutron scattering length: | 0.721 b/10-12 cm |
| Thermal neutron capture cross-section: | 84 sa / barns |
| Density: | 9840 kg/m-3 [298 K] |
| Melting point: | 1662.85°C / 1936°K |
| Boiling point: | 3394.85°C / 3668°K |
| Molar volume: | 17.78 cm3 |
| Thermal conductivity: | 16.4 [300 K] W m-1K-1 |
| Coefficient of linear thermal expansion: | 8.12 x 10-6 K-1 |
| Electrical resistivity: | 79.0 x 10-8 [298 K] Ωm |
| Mass magnetic susceptibility: | +1.3 x 10-9(s) kg-1m3 |
| Radi: | Lu3+ 85; atomic 173; covalent 156 |
| Electronegativity: | 1.27 (Pauling); 1.14 (Allred); ≤ 3.0 eV (absolute) |
| Effective nuclear charge: | 3.00 (Slater); 8.80 (Clementi); 12.68 (Froese-Fischer) |
| Number of Isotopes (incl. nuclear isomers): | 41 |
| Isotope mass range: | 154-> 182 |
| Biological role: | None, but acts to stimulate metabolism. |
|---|---|
| Toxicity | |
| Toxic intake: | n.a. |
| Lethal intake: | LD50 (chloride, oral, mouse) = 7100 mg Kg-1 |
| Hazards: | Lanthanum is mildly toxic by ingestion. |
| Level in humans | n.a. but very low |
| Daily dietary intake: | n.a. |
| Total mass of element in average [70 kg] person: |
n.a. but very low |
| Minerals: | ||||
|---|---|---|---|---|
| Mineral | Formula | Density | Hardness | Crystal apperance |
| Bastnäsite* | (La,Ce,etc.)CO3F | 4.9 | 4 - 5.5 | hex., vit./greasy yellow |
| Monazite* | (Ce, La, Nd, Th, etc.)PO4 | 5.20 | 5 - 5.5 | mon., waxy/vit. yellow-brown |
* Although not a major constituent, lutetium is present in extractable amounts.
| Chief ores: | monazite, bastnäsite |
|---|---|
| World production: | c. 10 tonnes/year |
| Producing areas: | USA, Brazil, India, Sri Lanka, Australia, China |
| Reserves: | c. 2 x 105 tonnes |
| Specimen: | available as ingots or powder. Safe! |
| Abundances | |
|---|---|
| Sun: | 5.8 (relative to H = 1 x 1012) |
| Earth's crust: | 0.51 ppm |
| Seawater | |
| Atlantic surface: | 1.4 x 10-7 ppm |
| Atlantic deep: | 2.0 x 10-7 ppm |
| Pacific surface: | 0.60 x 10-7 ppm |
| Pacific deep: | 4.1 x 10-7 ppm |
| Residence time: | 4000 years |
| Classification: | recycled |
| Oxidation state: | III |
Source: Emsley, J. (1998) The Elements (3rd Edition)
Other sizes and specifications on request