Deutsch
Wir sind führender Hersteller und Lieferant von Forschungsmaterialien
1794 von J. Gadolin in Åbo, Finnland, entdeckt.
[Nach Ytterby, Schweden, benannt]
French: yttrium
English: yttrium
Italian: ittrio
Spanish: ytrio
Beschreibung: Weiches, silberweißes Metall. Luftbeständig, da es durch eine Oxidhaut passiviert is. Verbrennt leicht. Reagiert mit Wasser unter Wasserstoffentwicklung. Verwendung: Rotphosphor für das Farbfernsehen; Supraleiter; magnetische Legierungen.
| State: | single crystal |
|---|---|
| Crystal structure: | hexagonal |
| Production method: | Floating zone |
| Standard size: | diameter 4mm thickness 1mm |
| Orientation: | (0001) |
| Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
| Polishing: | as cut, one or two sides polished |
| Roughness of surface: | <0.03µm |
| Purity: | 99.95% |
| Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
| Density: | 4.47 g/cm3 |
|---|---|
| Melting point: | 1521.85 °C / 1795 °K |
| Boiling point: | 3337.85 °C / 3611 °K |
| Molar volume: | 19.89 cm3 |
| Thermal conductivity: | 17.2 [300 K] Wm-1K-1 |
| Coefficient of linear thermal expansion: | 10.6 x 10-6 K-1 |
| Electrical resistivity: | 57.0x 10-8 [298 K] Wm |
| Mass magnetic susceptibility: | +2.70 x 10-8(s) kg-1m3 |
| Young's modulus: | 66.3 GPa |
| Rigidity modulus: | 25.5 GPa |
| Bulk modulus: | n.a. GPa |
| Poisson's ratio: | 0.265 GPa |
| Radii: | Y3+ 106; atomic 181; covalent 162 |
| Electronegativity: | 1.22 (Pauling); 1.11 (Allred); 3.19 eV (absolute) |
| Effective nuclear charge: | 3.00 (Slater); 6.26 (Clementi); 8.72 (Froese-Fischer) |
| Number of Isotopes (incl. nuclear isomers): | 32 |
| Issotope mass range: | 80 -> 99 |
| Crystal structure, (cell dimentions / pm), space group | hexagonal |
| X-ray diffraction: mass absorption coefficients: | CuKα 134 (µ/r) / cm2g-1 MoKα 100 (µ/r) / cm2g-1 |
| Neutron scattering length: | 0.775 b/10-12 cm |
| Thermal neutron capture cross-section: | 1.28 sa / barns |
| Biological role: | none |
|---|---|
| Toxicity | |
| Toxic intake: | n.a. |
| Lethal intake: | c. 15 g only one case reported) |
| Hazards: | Bismuth is regarded as one of the less toxic heavy metals and it is commonly used as a medicine for stomach upsets. Excess bismuth can cause mild kidney damage |
| Level in humans | |
| Blood: | 0.016 mg dm-3 |
| Bone: | <0.2 p.p.m. |
| Liver: | 0.015 - 0.33 p.p.m. |
| Muscle: | 0.32 p.p.m. |
| Daily dietary intake: | 0.005 - 0.02 mg |
| Total mass of element in average [70 kg] person: | < 0.5 mg |
| Mineral | Formula | Density | Hardness | Crystal apperance |
|---|---|---|---|---|
| Bastnäsite-Y | (Y, Ce)Co3F | 4.0 | 4 - 4.5 | tri. translucent brick-red |
| Fergusonite | YNbO4 | 5.7 | 5.5 - 6.5 | tet., vitreous, sub-metallic black |
| Gadolinite | Be2FeY2Si2O10 | 4.4 | 6.5 - 7 | mon., vit./greasy greenish-black |
| Polycrase-Y | Y(Ti, Nb)2(O, OH)6 | 5.0 | 5.5 - 6 | orth., sub-metallic black |
| Samarskite | AlO(OH) | 3.3 - 3.5 | 6.5 - 7 | orth., vit./resinous |
| Xenotime/TD> | YPO4 | 4.8 | 4 - 5 | tet., vit./resinous yellow-brown |
| Chief ore: | xenotime, bastnäsite, fergusonite, samarskite |
|---|---|
| World production: | 400 tonnes/year |
| Main mining areas: | xenitine in USA, bastnäsite in Russia, fergusonite in Norway, Russia, Madagascar |
| Reserves: | c. 9 x 106 tonnes |
| Specimen: | available as chieps, ingots or powder. Safe. |
| Abundances | |
|---|---|
| Sun: | 125 (relative to H = 1 x 1012) |
| Earth's crust: | 30 p.p.m. |
| Seawater: | |
| Residence time: | |
| Classification: | |
| Oxidation state: | III |