Wir sind führender Hersteller und Lieferant von Forschungsmaterialien
1794 von J. Gadolin in Åbo, Finnland, entdeckt.
[Nach Ytterby, Schweden, benannt]
French: yttrium
English: yttrium
Italian: ittrio
Spanish: ytrio
Beschreibung: Weiches, silberweißes Metall. Luftbeständig, da es durch eine Oxidhaut passiviert is. Verbrennt leicht. Reagiert mit Wasser unter Wasserstoffentwicklung. Verwendung: Rotphosphor für das Farbfernsehen; Supraleiter; magnetische Legierungen.
State: | single crystal |
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Crystal structure: | hexagonal |
Production method: | Floating zone |
Standard size: | diameter 4mm thickness 1mm |
Orientation: | (0001) |
Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
Polishing: | as cut, one or two sides polished |
Roughness of surface: | <0.03µm |
Purity: | 99.95% |
Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
Density: | 4.47 g/cm3 |
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Melting point: | 1521.85 °C / 1795 °K |
Boiling point: | 3337.85 °C / 3611 °K |
Molar volume: | 19.89 cm3 |
Thermal conductivity: | 17.2 [300 K] Wm-1K-1 |
Coefficient of linear thermal expansion: | 10.6 x 10-6 K-1 |
Electrical resistivity: | 57.0x 10-8 [298 K] Wm |
Mass magnetic susceptibility: | +2.70 x 10-8(s) kg-1m3 |
Young's modulus: | 66.3 GPa |
Rigidity modulus: | 25.5 GPa |
Bulk modulus: | n.a. GPa |
Poisson's ratio: | 0.265 GPa |
Radii: | Y3+ 106; atomic 181; covalent 162 |
Electronegativity: | 1.22 (Pauling); 1.11 (Allred); 3.19 eV (absolute) |
Effective nuclear charge: | 3.00 (Slater); 6.26 (Clementi); 8.72 (Froese-Fischer) |
Number of Isotopes (incl. nuclear isomers): | 32 |
Issotope mass range: | 80 -> 99 |
Crystal structure, (cell dimentions / pm), space group | hexagonal |
X-ray diffraction: mass absorption coefficients: | CuKα 134 (µ/r) / cm2g-1 MoKα 100 (µ/r) / cm2g-1 |
Neutron scattering length: | 0.775 b/10-12 cm |
Thermal neutron capture cross-section: | 1.28 sa / barns |
Biological role: | none |
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Toxicity | |
Toxic intake: | n.a. |
Lethal intake: | c. 15 g only one case reported) |
Hazards: | Bismuth is regarded as one of the less toxic heavy metals and it is commonly used as a medicine for stomach upsets. Excess bismuth can cause mild kidney damage |
Level in humans | |
Blood: | 0.016 mg dm-3 |
Bone: | <0.2 p.p.m. |
Liver: | 0.015 - 0.33 p.p.m. |
Muscle: | 0.32 p.p.m. |
Daily dietary intake: | 0.005 - 0.02 mg |
Total mass of element in average [70 kg] person: | < 0.5 mg |
Mineral | Formula | Density | Hardness | Crystal apperance |
---|---|---|---|---|
Bastnäsite-Y | (Y, Ce)Co3F | 4.0 | 4 - 4.5 | tri. translucent brick-red |
Fergusonite | YNbO4 | 5.7 | 5.5 - 6.5 | tet., vitreous, sub-metallic black |
Gadolinite | Be2FeY2Si2O10 | 4.4 | 6.5 - 7 | mon., vit./greasy greenish-black |
Polycrase-Y | Y(Ti, Nb)2(O, OH)6 | 5.0 | 5.5 - 6 | orth., sub-metallic black |
Samarskite | AlO(OH) | 3.3 - 3.5 | 6.5 - 7 | orth., vit./resinous |
Xenotime/TD> | YPO4 | 4.8 | 4 - 5 | tet., vit./resinous yellow-brown |
Chief ore: | xenotime, bastnäsite, fergusonite, samarskite |
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World production: | 400 tonnes/year |
Main mining areas: | xenitine in USA, bastnäsite in Russia, fergusonite in Norway, Russia, Madagascar |
Reserves: | c. 9 x 106 tonnes |
Specimen: | available as chieps, ingots or powder. Safe. |
Abundances | |
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Sun: | 125 (relative to H = 1 x 1012) |
Earth's crust: | 30 p.p.m. |
Seawater: | |
Residence time: | |
Classification: | |
Oxidation state: | III |