Wir sind führender Hersteller und Lieferant von Forschungsmaterialien
1817 von J.A. Arfvedson in Stockholm, Schweden, entdeckt. 1821 von W.T. Brande dargestellt.
[Grieschich, lithos = Stein]
French: lithium
English: lithium
Italian: litio
Spanish: litio
Beschreibung: Weiches, weißes, silberfarbiges Metall. Reagiert langsam mit Sauerstoff und Wasser. Verwendung für Legierungen (mit Al und Mg), Schmiermittel, Batterien, Gläser, Kernwaffen und in der Medizin.
State: | single crystal |
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Crystal structure: | cubic, bc |
Production method: | Czochralski |
Standard size: | diameter 5mm thickness 3mm |
Orientation: | (100), (110) and (111) |
Orientation accuracy: | <2°, <1°, <0.4° or <0.1° |
Polishing: | as cut |
Roughness of surface: | |
Purity: | 99.8% |
Typical analysis (ppm): | C 3 H < 1 O 9 N < 5 Cu 1.60 Fe 1.80 Ni < 1 Pb 0.30 Si 0.30 Ga, Hf and Ta are below the detection limit |
Density: | 0.53 g/cm3 |
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Melting point: | 180.54 °C / 453.69 °K |
Boiling point: | 1346.85 °C / 1620 °K |
Molar volume: | 13.00 cm3 |
Thermal conductivity: | 84.7 [300 K] Wm-1K-1 |
Coefficient of linear thermal expansion: | 56 x 10-6 K-1 |
Electrical resistivity: | 8.55x 10-8 [273 K] Wm |
Mass magnetic susceptibility: | +2.56 x 10-8(s) kg-1m3 |
Young's modulus: | 4.91 GPa |
Rigidity modulus: | 4.24 GPa |
Bulk modulus: | n.a. GPa |
Poisson's ratio: | 0.36 GPa |
Radii: | Li+ 78; atomic 152; covalent 123 |
Electronegativity: | 0.98 (Pauling); 0.97 (Allred); 3.01 eV (absolute) |
Effective nuclear charge: | 1.30 (Slater); 1.28 (Clementi); 1.55 (Froese-Fischer) |
Number of Isotopes (incl. nuclear isomers): | 5 |
Issotope mass range: | 5 -> 9 |
Crystal structure, (cell dimentions / pm), space group | cubic, bc |
X-ray diffraction: mass absorption coefficients: | CuKα 0.716 (µ/r) / cm2g-1 MoKα 0.217 (µ/r) / cm2g-1 |
Neutron scattering length: | - 0.190 b/10-12 cm |
Thermal neutron capture cross-section: | 70.5 sa / barns |
Biological role: | none, but lithium acts to stimulate metabolism and can control manic-depressive disorders |
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Toxicity | |
Toxic intake: | 20 - 200 g (see under hazards) |
Lethal intake: | LD50 (carbonate, oral, rat)=525 mg kg-1 |
Hazards: | Lithium is moderately toxic by ingestion but there are wide variations of tolerance. Even lithium carbonate, which is used in psychiatry, is prescribed at doses near to the toxic level. Some lithium c |
Level in humans | |
Blood: | 0.004 mg dm-3 |
Bone: | 1.3 p.p.m. |
Liver: | 0.025 p.p.m. |
Muscle: | 0.023 p.p.m. |
Daily dietary intake: | 0.1 - 2 mg |
Total mass of element in average [70 kg] person: | 7 mg |
Mineral | Formula | Density | Hardness | Crystal apperance |
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Amblygonite | (Li, Na)AlPO4(F, OH) | 3.1 | 5.5 - 6 | tric., vit./greasy white/grey |
Lepidolite | K(Li, Al)3(Si, Al)4O10(F, OH)2 | 2.85 | 2.5 - 3 | mon., pink/lilac, lamellae |
Petalite | LiAlSi4O10 | 2.4 | 6 - 6.5 | mon., vit./pearly colourless/white |
Spudomene | LiAlSi2O6 | 3.2 | 6.5 - 7.5 | mon., vit. colourless/grey |
Chief ore: | petalite, lepidolite |
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World production: | 39000 tonnes/year |
Main mining areas: | USA, lithium is also recovered from brines of Searles Lake in California |
Reserves: | 7.3 x 106 tonnes |
Specimen: | available as chunks, ingots, powder ribbon, rod, shot or wire. CARE ! |
Abundances | |
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Sun: | 10 (relative to H = 1 x 1012) |
Earth's crust: | 20 p.p.m. |
Seawater: | |
Residence time: | |
Classification: | accumulating |
Oxidation state: | I |