Terbium (Tb)

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Terbium 65Tb158.92


1843 von C. G. Mosander in Stockholm, Schweden, entdeckt.

[Nach Ytterby, Schweden, benannt]

French: terbium
English: terbium
Italian: terbio
Spanish: terbio


Beschreibung: Silberweißes Metall, seltenes Element der Lanthanoidgruppe. Oxidiert langsam an der Luft, reagiert mit kaltem Wasser. Verwendung: Laser, Leuchtstoffe.

  


Further Materials properties

 

Crystal structure:

(cell dimensions/pm), space group, 
Tb orthorhombic (a=359.0, b=626.0, c=571.5) Cmcm
α-Tb h.c.p. (a=360.10, c=569.36) P63/mmc
β-Tb b.c.c. (a=402) Im3m
T (α -> orthorhombic) = 220 K, T (α -> β) = 1590 K

X-ray diffractions mass absorption coefficients: CuKa 273 (µ/r) / cm2g-1
MoKa 67.5 (µ/r) / cm2g-1
Neutron scattering length: 0.738 b/10-12 cm
Thermal neutron capture cross-section: 23.4 sa / barns
Density: 8229 kg/m-3 [293 K]
Melting point: 1355.85°C / 1629°K
Boiling point: 3122.85°C / 3396°K
Molar volume: 19.31 cm3
Thermal conductivity: 11.1 [300 K] W m-1K-1
Coefficient of linear thermal expansion: 7.0 x 10-6 K-1
Electrical resistivity: 114 x 10-8 [295 K] Ωm
Mass magnetic susceptibility: +1.15 x 10-5(s) kg-1m3
Radi: Tb4+ 81Tb3+ 97; atomic 178; covalent 159
Electronegativity: n.a. (Pauling); 1.10 (Allred); ≤ 3.2 eV (absolute)
Effective nuclear charge: 2.85 (Slater); 8.30 (Clementi); 11.39 (Froese-Fischer)
Number of Isotopes (incl. nuclear isomers): 31
Isotope mass range: 145 -> 165

 

 


Biological data

 

Biological role: None.
Toxicity
Toxic intake: n.a.
Lethal intake: LD50 (chloride, oral, mouse) = >5100 mg Kg-1
Hazards: Terbium is mildly toxic by ingestion, and is a skin and eye irritant.
Level in humans
Organs: n.a., but low 
Daily dietary intake: n.a.
Total mass of element in average
[70 kg] person:

n.a., but very low 


Geological data

 

Minerals:
MineralFormulaDensityHardnessCrystal apperance
Monazite*  (Ce, La, Nd, Th, etc.)PO4 5.20  5 - 5.5  mon., waxy/vit. yellow-brown

* Although not a major constituent, terbium is present in extractable amounts.

Chief ores:  monazite
World production:  c. 10 tonnes/year
Producing areas:  USA, Brazil, India, Sri Lanka, Australia
Reserves:  c. 3 x 10tonnes
Specimen:  available as chips or ingots. Safe. Terbium powder is very irritating to skin and eyes. Care!

 

Abundances  
Sun: n.a. (relative to H = 1 x 1012)
Earth's crust: 1.1 ppm
Seawater
Atlantic surface: 1 x 10-7 ppm
Atlantic deep: 1.5 x 10-7 ppm
Pacific surface: 0.8 x 10-7 ppm
Pacific deep: 2.5 x 10-7 ppm
Residence time: n.a.
Classification: recycled
Oxidation state: III

  Source: Emsley, J. (1998) The Elements (3rd Edition)

Other sizes and specifications on request


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H
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F
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